KMS Chongqing Institute of Green and Intelligent Technology, CAS
| Function of TiO2 Lattice Defects toward Photocatalytic Processes: View of Electronic Driven Force | |
Cui, Huanan1; Liu, Hong1  ; Shi, Jianying1; Wang, Chuan2
| |
| 2013 | |
| 摘要 | Oxygen vacancies and Ti-related defects (OTDs) are the main lattice defects of TiO2, which have great influence on its photocatalytic activity. To understand the relationship between the defects and photocatalytic activities, detailed discussions based on the electronic driven force provided by these defects are carried out during the three commonly accepted processes in photocatalytic reactions. It is found that these defects inevitably (i) influence the energy structure of the pristine TiO2 as the isolate acceptor/donor level or hybrid with the original orbital, (ii) provide a disordered short-range force that confuses the charge carriers transferring to surface active sites, (iii) act not only as the surface active sites for trapping the charge carriers but also as the main chemisorption sites for O-2, H2O, and organic species. These effects of the defects make them one of the key factors that determine the efficiency of heterogeneous photocatalysis. Clarifying the role of the defects will further facilitate the exploration and the construction of high-performance photocatalysts for practical applications. |
| DOI | 10.1155/2013/364802 |
| 发表期刊 | INTERNATIONAL JOURNAL OF PHOTOENERGY
 |
| ISSN | 1110-662X |
| 页码 | 16 |
| 通讯作者 | Liu, H (reprint author), Sun Yat Sen Univ, Sch Chem & Chem Engn, Guangdong Higher Educ Inst, Key Lab Environm & Energy Chem, Guangzhou 510275, Guangdong, Peoples R China. |
| 收录类别 | SCI |
| WOS记录号 | WOS:000329813300001 |
| 语种 | 英语 |
