KMS Chongqing Institute of Green and Intelligent Technology, CAS
Sintering temperature dependence of thermoelectric performance in CuCrSe2 prepared via mechanical alloying | |
Yan, Yanci1; Guo, Lijie1; Zhang, Zhi3; Lu, Xu1; Peng, Kunling1,2; Yao, Wei1; Dai, Jiyan3; Wang, Guoyu2; Zhou, Xiaoyuan1 | |
2017-01-15 | |
摘要 | CuCrSe2 compounds were synthesized by mechanical alloying followed by annealing and spark plasma sintering at temperatures of 873 K, 923 K, 973 K and 1023 K. Our investigation revealed that high SPS temperature (above 973 K) is the key to obtaining CuCrSe2 single phase completely free of a metallic secondary phase CuCr2Se4. The ultralow thermal conductivity caused by the Cu ions disorder, complex layered structure and dislocation leads to the favorable thermoelectric performance in CuCrSe2 compound. A maximum ZT value over 0.75@873 K is achieved in the absolutely pure sample sintered at 1023 K. (C) 2016 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved. |
关键词 | CuCrSe2 Single phase Layered structure PLEC |
DOI | 10.1016/j.scriptamat.2016.09.016 |
发表期刊 | SCRIPTA MATERIALIA |
ISSN | 1359-6462 |
卷号 | 127页码:127-131 |
通讯作者 | Zhou, XY (reprint author), Chongqing Univ, Coll Phys, Chongqing 401331, Peoples R China. |
收录类别 | SCI |
WOS记录号 | WOS:000386407100029 |
语种 | 英语 |